Platinum‐Group Element Results for Two Cobalt‐Rich Seamount Crust Ultra‐Fine Reference Materials: MCPt‐1and MCPt‐2     

Yimin Wang  Xiaohong Wang  Wenjun Qu  Yushu Gao  Tiexin Gu  Xingtao Fan  S.I. Andreev  Xuefa Shi 《Geostandards and Geoanalytical Research》2011,35(3):341-352

Two Co‐rich seamount crust reference materials, MCPt‐1 and MCPt‐2, were prepared using ultra‐fine particle size milling technique and characterised for the platinum‐group elements (PGEs). The raw material for these two reference materials was collected separately from the Magellan seamounts of the western Pacific Ocean and the seamounts of the central Pacific Ocean by Russian and Chinese scientists. First, they were ground by ball mill to a ?200 mesh powder, then further processed by ultra‐fine jet mill and well‐mixed. The particle size distributions of the samples were tested by a laser particle analyser; the average particle size was 1.8 and 1.5 μm (equal to about 2000 mesh) respectively. The homogeneity of six major and minor elements in these two materials was tested at the milligram level of sampling mass by high‐precision wavelength dispersive X‐ray fluorescence (XRF) spectrometry and at the microgram level of sampling mass by electron probe microanalyser. The homogeneity of more than forty trace elements, including Pt, was tested at the microgram level of sampling mass by LA‐ICP‐MS. Except for Rh, all PGEs were determined by isotope dilution‐ICP‐MS. Platinum in MCPt‐1 and MCPt‐2 was characterised as certified values, whereas the other five PGEs in MCPt‐1 and MCPt‐2 were reported as reference values. In addition, the information values of sixty‐two major, minor and trace elements were obtained by XRF, ICP‐AES and ICP‐MS. The minimum sampling mass for the determination of PGEs was 1 g, while the minimum sampling mass for the determination of the other elements was 2–5 mg.  相似文献   

贺兰山北段贺兰山岩群富铝片麻岩碎屑锆石LA-ICP-MS U-Pb定年及区域对比   总被引：6，自引：1，他引：5  

校培喜  由伟丰  谢从瑞  李平  白生明 《地质通报》2011,30(1):26-36

贺兰山北段贺兰山岩群中发育一套富铝片麻岩,Al2O3含量较高,总体与粘土质岩石化学成分相似,显示孔兹岩系的特征,变质矿物组合主要为石榴子石、堇青石、硅线石、十字石、紫苏辉石等,变质级别达角闪岩相—麻粒岩相。从宗别立岩组含石榴矽线黑云二长片麻岩中选取100粒各种类型的锆石进行了LA-ICP-MS U-Pb同位素测年,获得47个测年数据,锆石年龄多数介于1.80~2.15Ga之间,峰值为2.00~2.05Ga。碎屑锆石年龄频谱图与鄂尔多斯地块北缘的集宁岩群和乌拉山岩群十分相似,总体与吕梁构造运动的时限一致,为华北克拉通成熟陆壳演化阶段的产物,证明孔兹岩系形成于古元古代,之后长期处于稳定状态,很少受到构造热事件的干扰。  相似文献   

Petrological and Geochemical Constraints on the Protoliths of Serpentine‐Magnetite Ores in the Zhaoanzhuang Iron Deposit,Southern North China Craton     

MENG Jie  LI Houmin  LI Lixing  SANTOSH M.  SONG Zhe  YANG Xiuqing 《《地质学报》英文版》2018,92(2):627-665

The uncommon Mg-rich and Ti-poor Zhaoanzhuang serpentine-magnetite ores within Taihua Group of the North China Craton(NCC) remain unclear whether the protolith was sourced from ultramafic rocks or chemical sedimentary sequences. Here we present integrated petrographic and geochemical studies to characterize the protoliths and to gain insights on the ore-forming processes. Iron ores mainly contain low-Ti magnetite(TiO_2 ~0.1 wt%) and serpentine(Mg#=92.42–96.55), as well as residual olivine(Fo=89–90), orthopyroxene(En=89–90) and hornblende. Magnetite in the iron ores shows lower Al, Sc, Ti, Cr, Zn relative to that from ultramafic Fe-Ti-V iron ores, but similar to that from metamorphic chemical sedimentary iron deposit. In addition, interstitial minerals of dolomite, calcite, apatite and anhydrite are intergrown with magnetite and serpentine, revealing they were metamorphic, but not magmatic or late hydrothermal minerals. Wall rocks principally contain magnesian silicates of olivine(Fo=83–87), orthopyroxene(En=82–86), humite(Mg#=82–84) and hornblende [XMg=0.87–0.96]. Dolomite, apatite and anhydrite together with minor magnetite, thorianite(Th-rich oxide) and monazite(LREE-rich phosphate) are often seen as relicts or inclusions within magnesian silicates in the wall rocks, revealing that they were primary or earlier metamorphic minerals than magnesian silicates. And olivine exists as subhedral interstitial texture between hornblende, which shows later formation of olivine than hornblende and does not conform with sequence of magmatic crystallization. All these mineralogical features thus bias towards their metamorphic, rather than magmatic origin. The dominant chemical components of the iron ores are SiO_2(4.77–25.23 wt%), Fe_2O_3 T(32.9–80.39 wt%) and MgO(5.72–27.17 wt%) and uniformly, those of the wall rocks are also SiO_2(16.34–48.72 wt%), Mg O(16.71–33.97 wt%) and Fe_2O_3 T(6.98–30.92 wt%). The striking high Fe-Mg-Si contents reveal that protolith of the Zhaoanzhuang iron deposit was more likely to be chemical sedimentary rocks. The distinct high-Mg feature and presence of abundant anhydrite possibly indicate it primarily precipitated in a confined seawater basin under an evaporitic environment. Besides, higher contents of Al, Ti, P, Th, U, Pb, REE relative to other Precambrian iron-rich chemical precipitates(BIF) suggest some clastic terrestrial materials were probably input. As a result, we think the Zhaoanzhuang iron deposit had experienced the initial Fe-Mg-Si marine precipitation, followed by further Mg enrichment through marine evaporated process, subsequent high-grade metamorphism and late-stage hydrothermal fluid modification.  相似文献   

四川盆地三叠系隐伏钾盐层识别与预测方法研究     

张研  李萌  龚大兴  陈科贵  丁峰 《地质学报》2015,89(11):1970-1982

本文首先通过总结四川盆地钾盐(杂卤石、富钾卤水)的测井响应特征,提出钾盐的测井组合识别法;其次为满足大数据量预测处理需求,介绍了钾盐的测井旋回地层学预测法,该方法具有处理速度快,预测准确度高的特点;最后在实际资料处理与解释中,本文采用了测井旋回地层学法初步预测潜在含钾层段,测井组合识别法再对存疑含钾层段精细排查的技术组合策略,对四川盆地三叠系钾盐资源分布进行了预测,并根据预测结果,划分了4期咸化旋回,指明了3个成钾期,圈定了4个成钾有利区。  相似文献   

安徽巢北地区栖霞组臭灰岩段富有机质成因探讨   总被引：3，自引：0，他引：3  

陆鹿  李壮福  康鹏  张新 《地质论评》2014,60(1):71-79

以安徽巢北地区二叠纪栖霞组臭灰岩段为研究对象,从岩石学、古生物学及沉积学特征出发,探讨臭灰岩段富有机质与风暴事件沉积之间的关系。臭灰岩段岩性整体为灰黑色中厚层状石灰岩,层间夹数毫米至数厘米厚灰黑色钙质泥岩,整套岩层富含有机质;其中生物化石丰富,整体为热带、亚热带正常盐度浅水生物组合为特征;为正常浅海碳酸盐岩台地沉积,沉积期表现为一个明显的海侵过程,并受风暴作用的频繁扰动。臭灰岩段沉积环境并非“贫氧或缺氧”条件,而是正常富氧环境。富有机质特征一方面得益于沉积期较高的生物产率,同时还与风暴事件沉积作用密切相关,即在风暴作用下,沉积物发生快速堆积,有机质未来得及与富氧水体发生长期接触即被埋藏覆盖,从而导致有机质被良好保存,形成臭灰岩段富有机质特征。风暴作用频发与研究区臭灰岩段沉积期所处的低纬度特征有关。  相似文献   

镇泾油田红河105—1057井区微生物异常与含油气性关系          下载免费PDF全文

袁志华  张敏 《江苏地质》2012,36(1):92-98

油气微生物勘探（MPOG）是地表油气藏评价的一个分支,主要研究近地表土壤层中微生物异常与地下深部油气藏的相关关系,它以成本低廉,简便快速,多解性小的特点,在镇泾油田得到充分的验证。在镇泾油田内,以微生物异常为基础,结合已有的区域油气地质、钻井和测井等资料,对微生物异常区域进行分析研究,重点解释说明了镇泾油田红河105—1057井区长821小层与油气异常的关系,并圈定出2个异常区,其异常连片分布,异常区的异常平均值较高,反映本工区内油藏控制面积较大。本工区天然气微生物异常整体水平较低,且基本上与油藏微生物异常区吻合,异常区零星分布,表明本工区的天然气多系原油溶解气。最后对工区油藏分级评价,并根据微生物勘探结果和地质特征等综合因素,在工区部署3口建议井。  相似文献   

华南富铀花岗岩和产铀花岗岩特征   总被引：4，自引：0，他引：4  

冯明月  何德宝 《铀矿地质》2012,(4):199-207

文章简要叙述了我国南方5省(区)富铀花岗岩和产铀花岗岩概况,详细讨论了产铀花岗岩的主要特征:断裂构造发育,蚀变作用非常强烈,经常有二云母花岗岩出现,中基性和酸性脉岩比较发育。正是这些特征,决定了它们产出铀矿床的能力。  相似文献   

利用石膏产状研究汶东盐湖相沉积与烃源岩特征   总被引：1，自引：1，他引：0  

刘庆  张林晔  宋国奇  宋长玉  王茹 《高校地质学报》2009,15(3):371

根据石膏矿物类型和产状以及其它相标志,对汶东凹陷汶ZK16 钻孔的古近系盐湖相地层进行了沉积相分析,并结合有机地球化学分析,对不同沉积相的烃源岩开展了地球化学评价。汶东凹陷石膏矿物组合较好的反映了古盐湖沉积环境、水深、盐度和底水含氧量等的变化,不同的石膏矿物组合对应着不同的沉积相和不同质量的烃源岩,其中干化泥坪相和盐化泥坪相石膏矿物组合以分散胶结状和结核状为主,其烃源岩有机质丰度较低,发育非烃源岩到差烃源岩;干盐湖相石膏矿物组合以肠状石膏和透镜状石膏为主,烃源岩有机质丰度较高,发育好到优质烃源岩;而深水盐湖相石膏矿物以纹层状石膏为主,烃源岩有机质丰度高,总体达到优质烃源岩的标准。据此,建立了盐湖相烃源岩的发育模式。该模式对于中国第三系盐湖烃源岩,特别是高演化程度的盐湖相烃源岩原始烃源岩类型研究具有重要的指导意义。  相似文献   

Ore Group Classification - A Case Study from Ingaldhal Sulphide Deposit, Karnataka Craton, India     

Joju P. Antony   《Gondwana Research》1999,2(1):67

All varieties of base metal sulphide deposits may be classified using base metal ratios viz. Copper Ratio (CR=100Cu/{Cu+Zn}), Zinc Ratio (ZR=100Zn/{Zn+Pb}) and Lead Ratio (PR=100Pb/{Pb+Cu}). Based on this ore group classification an attempt has been made to identify ore groups present in the late Archaean volcanic associated Ingaldhal Sulphide Deposit (ISD) of Karnataka Craton. Using base metal ratios (CR, ZR and PR) five distinct fields are suggested: Cu, Cu-Zn, Cu-Zn-Pb, Zn-Cu and Zn-Cu-Pb/Zn-Pb-Cu with their associated geological and geochemical characteristics. A transitional change in the ore groups is observed from the North Block (Cu rich groups; CR>50) to South Block (Zn and Pb dominated groups; CR<50) and the Main Block is represented by all the five ore groups.This classification may be useful as a pointer in the exploration of polymetallic base metal deposits. Copper rich groups (Cu, Cu-Zn and Cu-Zn-Pb) exhibit high concentration of Bi and Co, and low CaO and Cd whereas the Zn rich groups (Zn-Cu and Zn-Cu-Pb/Zn-Pb-Cu) show high CaO and Cd, and low Bi and Co. The CR of most of the ore groups exhibit a sympathetic relation with Co and Ag. A preliminary attempt has been made for better understanding of ore group genesis of ISD by integrating ore group characteristics with deduced geothermometry.  相似文献   

Rhenium–Osmium Isotope Measurements in Marine Shale Reference Material SBC‐1: Implications for Method Validation and Quality Control     

Jie Li  Lu Yin 《Geostandards and Geoanalytical Research》2019,43(3):497-507

In this study, the USGS black shale reference material SBC‐1 was investigated as a matrix‐matched reference material for both intra‐laboratory calibration and inter‐laboratory comparison of high‐precision Re‐Os dating for organic‐rich sedimentary rocks. This reference material was analysed for Re‐Os isotopic composition by three digestion protocols – inverse aqua regia, CrO₃‐H₂SO₄ and H₂O₂‐HNO₃. The results for SBC‐1 obtained by inverse aqua regia digestion yielded similar Re mass fractions but slightly (~ 5%) higher Os mass fractions and lower ¹⁸⁷Os/¹⁸⁸Os values than the CrO₃‐H₂SO₄ and H₂O₂‐HNO₃ digestions. The data set of inverse aqua regia digestion exhibited strong correlations in plots of ¹⁸⁷Os/¹⁸⁸Os vs. 1/¹⁹²Os and ¹⁸⁷Os/¹⁸⁸Os vs. ¹⁸⁷Re/¹⁸⁸Os, which may signify the incorporation of detrital Re and Os into organic matter in the Re‐Os system. Similar correlations were also observed for the CrO₃‐H₂SO₄ digestion data set, but not for that of H₂O₂‐HNO₃. The data indicate that there is an amount of non‐hydrogenous Os in SBC‐1 and that CrO₃‐H₂SO₄ and H₂O₂‐HNO₃ digestions would minimise liberation of the non‐hydrogenous Os component. We propose that SBC‐1 may be a more suitable reference material to monitor the influence of detrital Re and Os on Re‐Os isochron age data, especially for samples with less organic matter and more siliceous detritus.  相似文献